The letter-cluster that DOES NOT belong to the group is WNI.
Explanation:
This pattern is based on opposite letters in the English alphabet (pairs that add up to 27 in position value, such as A-Z, B-Y, etc.):
RIZ: R and I are opposites. (Z is left over).
EVM: E and V are opposites. (M is left over).
ARI: A and R are not opposites, but R and I are opposites. It contains an opposite pair.
WNI: W, N, and I do not contain any opposite letter pairs (W pairs with D, N pairs with M, and I pairs with R).
Alternatively, looking closely at the specific structure of the first three pairs:
R ↔ I (Opposite pair) + Z
E ↔ V (Opposite pair) + M
A + R ↔ I (Opposite pair)
Every group contains exactly one pair of alphabet opposites except WNI.