Which of the following will give a pleasant smell of ester when heated with ethanol and small quantity of sulphuric acid ?
ACH₂-CH₂-OH
BCH₃-OH
CCH₃-COH
DCH₃-COOH
Answer:
D. CH₃-COOH
Read Explanation:
The correct answer is indeed CH₃-COOH, or Acetic Acid.
When Acetic Acid (CH₃-COOH) is heated with ethanol (C₂H₅OH) and a small quantity of sulfuric acid (H₂SO₄), it undergoes an esterification reaction to form Ethyl Acetate (CH₃-COO-C₂H₅), which has a pleasant, fruity smell.
The reaction is:
CH₃-COOH + C₂H₅OH → CH₃-COO-C₂H₅ + H₂O
This reaction is a classic example of esterification, and the resulting ester has a characteristic pleasant smell.